Catalytic Hydrolysis of Lipophilic Amino Acid Esters by Metallomicelles as Carboxypeptidase A Models

Metallondcellesasthemodelofhydrolyticmetalloenzymes.havebegunrecently'.Exam-plesarethemetal-ioncomplexesoflipophilicinddazoles2andpyridines'co-ndcelledwithsurfactantS.Hereinwereportthecomplexesofanovelmacrocyclicl2-membereddioxotetradrineligandbearingbis-hydroxygroupsasfunctionalpendantSwhichcanmindcthecatalyticfunctionofcarboxypeptidaseAinndcellarmedia.2,6-Dioxo-l,4,7,lo-tetraazacyclo1(O.2Og,1.onuno1)'anddodecylglycidylether(O.54g,2.2nunol)'wererefluxedinEtOH(3OoInL)for24h.Thesolventwase…     

Manufacturing at Nanoscale: Top-Down,Bottom-up and System Engineering

The current nano-technology revolution is facing several major challenges: to manufacture nanodevices below 20 nm, to fabricate three-dimensional complex nano-structures, and to heterogeneously integrate multiple functionalities. To tackle these grand challenges, the Center for Scalable and Integrated NAno-Manufacturing (SINAM), a NSF Nanoscale Science and Engineering Center, set its goal to establish a new manufacturing paradigm that integrates an array of new nano-manufacturing technologies, including the plasmonic imaging lithography and ultramolding imprint lithography aiming toward critical resolution of 1–10 nm and the hybrid top-down and bottom-up technologies to achieve massively parallel integration of heterogeneous nanoscale components into higher-order structures and devices. Furthermore, SINAM will develop system engineering strategies to scale-up the nano-manufacturing technologies. SINAMs integrated research and education platform will shed light to a broad range of potential applications in computing, telecommunication, photonics, biotechnology, health care, and national security.     

新的不动点定理及应用

本文获得了几个压缩型映射的不动点定理,改进了相应文献的结果．应用该定理,给出了一类时滞积分方程的正概周期解的存在性结果．推广了已有的结果．     

Upconversion luminescence of Er/Yb-codoped natrium-germanium-bismuth glasses

The absorption and upconversion fluorescence spectra of a series of Er³⁺/Yb³⁺-codoped natrium-germanium-bismuth glasses have been studied. The transition probabilities, excited state lifetimes, and the branching ratios have been predicted for Er³⁺ based on the Judd-Ofelt theory. At room temperature, an upconversion efficiency of 6.1×10⁻² has been obtained for the green emission from the glass with 0.5 wt% Er₂O₃ and 3.0 wt% Yb₂O₃ pumped by 980 nm radiation with an intensity of 270 W/cm². And the “standardized” efficiency for green upconversion light is higher than that reported in lead-germanate, lead-tellurite-germanate, and silicate glasses. The results indicate that the Er³⁺/Yb³⁺-codoped natrium-germanium-bismuth oxide glass may be a potential material for developing upconversion optic devices.     

热处理参数对溶胶-凝胶法制备氧化锌薄膜特性的影响

采用溶胶-凝胶旋涂法在Si(111)衬底上生长了ZnO薄膜，并用荧光光谱、原子力显微镜和XRD对ZnO薄膜样品进行了分析.结果表明，溶胶-凝胶旋涂法制备的ZnO薄膜为纤锌矿结构，其c轴取向程度与热处理温度有很大的关系.当热处理温度小于550℃时，氧化锌薄膜在室温下均有较强的紫外带边发射峰，而可见波段的发射很弱；当热处理温度高于550℃时，可见波段发射明显增强.对经过不同时间热处理的ZnO薄膜样品分析表明，氧化锌薄膜的荧光特性及表面形貌与热处理时间也有很大关系，时间过短可见波段的发射较强，但时间过长会导致晶 关键词： ZnO薄膜 光致发光     

Ce3+离子激活的SrB4O7的VUV光谱

Ce³⁺只有一个4f电子,具有最简单的4f¹5d⁰基态结构,其激发光谱直接反映了5d轨道的能量状态。由于同一基质晶格相同格位上不同稀土离子受基质晶体场影响相近,所以根据Ce³⁺离子的光谱可以推测和分析其他稀土离子的5d轨道能量,是研究其他稀土离子f-d跃迁的基础。采用高温固相法合成了Ce³⁺离子激活的SrB₄O₇发光体,测定了样品在130~350nm波长范围的激发光谱和相应的发射光谱。指认了VUV激发光谱上Ce³⁺离子的5个4f¹→4f⁰5d¹跃迁激发带,讨论了SrB₄O₇的基质吸收带和Ce³⁺的5d轨道在SrB₄O₇中的晶体场劈裂、5d轨道能级重心及SrB₄O₇:Ce³⁺的发射光谱和Stokes位移。     

An improved broad-spectrum room acoustics model including diffuse reflections

More and more literature has paid attention to the diffuse reflections in enclosed space during the past few years. In this paper, the current computer models including diffuse reflections have been reviewed briefly at first. Then, to realize the broad-spectrum simulation for enclosed sound fields including diffuse reflections, an improved ray-tracing algorithm, which combines the splitting coefficient diffusion model and a dynamic sound ray receiving method, has been given. The algorithm can deal with broad frequency bands simultaneously by using the frequency independent splitting coefficient. To test the algorithm and also to investigate the significance of the diffuse reflections in enclosed sound fields, experiments have been made in three spaces including a virtual room and two real rooms. The results and discussions have validated the applicability of the improved algorithm and they have also shown that diffuse reflections can improve room acoustic prediction, although it not always promote a sound field to be more diffused.     

自发喇曼成像法在线测量流场组分浓度(II)

 介绍了利用自发Raman散射光谱测量低压气流组分绝对浓度的方法，在流动状态下得到了不同压力下的自发喇曼散射光谱，检测最低压力为133帕；对于含N₂氧气流在已知N₂浓度时实时标定检测了O₂的绝对浓度，测量误差小于8%。     

催化动力学测定食品中痕量甲醛

在H2SO4介质中,甲醛可灵敏催化溴酸钾氧化中性红的褪色反应,研究了该指标反应的动力学参数,建立了动力学光度法测定痕量甲醛的新方法。该方法的检出限为4.08×10-9g/mL,线性范围在0-1.0μg/25mL。用水蒸汽蒸馏法蒸馏甲醛用于食品中甲醛的测定,结果满意。     

部分相干光学成像系统的光学传递函数和像质评价准则

根据光学成像理论，建立了部分相干成像光学系统的光学传递函数。该函数与非相干成像光学系统传递函数相同，因而部分相干成像和非相干成像两者的光学系统波面像差公差标准也是相同的。这一点解释了显微镜光学系统的光学设计惯用法则：镜头像差公差标准的选择，并不因为采用成像照明方式的不同而有所差异。